It simply takes the information and files it away into little

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The reversible reactions of TNBCl with primary amines are found to be: rapid formation of the 3 adduct, followed by isomerisation to the thermodynamically more stable 1 adduct, followed by equilibration with the conjugate base formed by transfer of a side chain proton. With the secondary amines piperidine and pyrrolidine, adduct formation at the 1 position is not observed because the presence of two bulky groups at the 1 position is sterically unfavourable. The adduct forming reactions occur via zwitterionic intermediates and it is shown that proton transfers between these species and amines may be kinetically significant.

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